Destination-aware metric based social routing for mobile opportunistic networks

Wireless Networks - Although centrality is widely used to differentiate the importance of nodes for social-aware routing in mobile opportunistic networks (MONs), it is destination-agnostic since...     

新型防屈曲高强钢腹板可更换钢连梁抗震性能研究

文章率先提出一种新型防屈曲高强钢腹板可更换钢连梁(简称“新型钢连梁”)：腹板采用高强钢，可提高钢连梁的屈服抗剪强度，连梁变形减小，从而减小可更换结构整体变形，便于更换；加劲肋紧贴腹板(但不焊接)提供约束，仅与上下翼缘焊接，可减少60%以上的焊接量。其次，设计并开展了11个试件的拟静力试验，研究了加劲肋间距(规范限值dmax、0.85dmax)、腹板厚度(6mm、8mm)、腹板钢材强度(Q460、Q550)和构造形式(加劲肋与腹板贴紧或焊接)等参数对新型钢连梁抗震性能的影响。试验结果表明：试件均发生剪切破坏；满足加劲肋间距限值的新型钢连梁，滞回曲线饱满，峰值时腹板未发生鼓曲且极限转角均超过0.1rad，大于规范限值0.08rad，表现出良好的耗能和变形能力；缩小加劲肋间距、增加腹板厚度或提高腹板钢材强度，新型钢连梁刚度及承载力提高；新型钢连梁峰值承载力较传统构造试件低约5%。最后，基于试验结果建立了有限元模型并开展了分析，研究结果表明：对腹板采用Q460、Q550高强钢材的新型钢连梁，峰值承载力计算时超强系数建议取1.43(长度比为0.5～1.0)或1.39(长度比为1.0～1.6)、1.25，以期为实际工程设计提供依据。     

Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.     

Study on the removal of olefins from naphtha by clay loaded with trifluoromethanesulfonic acid

Journal of Porous Materials - In this work, a trifluoromethanesulfonic acid (TFOH) modified clay (TFOH-Clay) was developed for the removal of trace olefins in heavy naphtha. 5%TFOH-Clay can...     

塔里木盆地塔西南坳陷柯东构造带甫沙4井原油来源及充注过程

甫沙4井位于塔里木盆地塔西南坳陷昆仑山前冲断带的柯东构造带上，北部和东部分别发育有柯克亚和柯东1井油气田。为研究甫沙4井原油来源与充注过程，对原油样品和连续抽提后的含油砂样各组分（游离态、束缚态、包裹体）进行GC、GC?MS和 GC?IRMS分析，与柯克亚凝析油气田油样进行油—油对比。结果表明：甫沙4井晚期充注原油组分具有C_29?32重排藿烷、重排甾烷和Ts相对含量高，C_27?29甾烷ααα 20R分布呈反“L”型，以及正构烷烃单体碳同位素值较低等特征，与柯克亚凝析油气田来源于二叠系普司格组（P_2?3p）烃源岩的主体原油（I类）地球化学特征一致。而早期充注的原油组分具有重排藿烷、重排甾烷和Ts相对含量较低，C_27?29甾烷ααα 20R分布呈“V”型，以及正构烷烃单体碳同位素值较高等特征，与柯克亚凝析油气田来源于中—下侏罗统湖相泥岩的II类原油地球化学特征一致。甫沙4井经历3个阶段成藏过程：①在上新世，二叠系烃源岩于生油晚期阶段生成的I类原油运移至柯克亚构造带或柯东构造带深部形成油藏；②在更新世早期，侏罗系烃源岩于生油早—中期生成的II类原油运移至甫沙4井白垩系储层；③在第四纪，强烈的构造作用使深部I类原油沿断裂调整进入甫沙4井白垩系储层。最终造成甫沙4井白垩系储层II类原油先充注，I类原油后充注的特殊现象。